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Laves Phases
 
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Fundamental Questions
 
 
Some fundamental questions - many of them strongly correlated - concerning the nature of Laves phases have to be answered:

Which binary systems form stable or metastable Laves phases, and which phases are thermodynamic competitors?

 

Which ternary Laves phases are accessible via binary ones as terminal solid solutions, and which are intermediate ternary Laves phases?

Which Laves phase polytypes are thermodynamically stable or metastable?

Which factors determine the homogeneity ranges?

How do phase transformations between different polytypes proceed?

What is the kinetics of the phase transformations between different polytypes?

What is the character of chemical bonding as a function of the components, composition, structure, temperature and pressure?

What is the relation between physical properties and real structures of the polytypes?

What is the influence of impurities?
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